Crystal structure of (4-fluoro-phenyl-κC (1))iodido-(N,N,N',N'-tetra-methyl-ethylenedi-amine-κ(2) N,N')palladium(II)

Jin-Jin Yan; Chang-Ge Zheng

doi:10.1107/S2056989015008014

Crystal structure of (4-fluoro-phenyl-κC (1))iodido-(N,N,N',N'-tetra-methyl-ethylenedi-amine-κ(2) N,N')palladium(II)

Acta Crystallogr E Crystallogr Commun. 2015 Apr 30;71(Pt 5):m124-5. doi: 10.1107/S2056989015008014. eCollection 2015 May 1.

Authors

Jin-Jin Yan¹, Chang-Ge Zheng¹

Affiliation

¹ School of Chemical and Material Engineering, Jiangnan University, 1800 Lihu Road, Wuxi, Jiangsu Province 214122, People's Republic of China.

Abstract

In the title compound, [Pd(C6H4F)I(C6H16N2)], the Pd(II) atom is coordinated by two N atoms from the N,N,N',N'-tetra-methyl-ethylenedi-amine ligand, a C atom of the 4-fluoro-phenyl group and an iodide ligand in a distorted square-planar geometry, with an average deviation from the least-squares plane through the ligand donor atoms of 0.0159 (2) Å. The angles about the Pd(II) atom range from 83.35 (16) to 178.59 (11)°. In the crystal, weak C-H⋯F and C-H⋯I hydrogen bonds link the mol-ecules into sheets in the bc plane.

Keywords: crystal structure; hydrogen bonding; palladium(II) complex; single-crystal X-ray study; square-planar coordination; tetramethylethylenediamine.