Abstract
A rhodium-catalyzed [2 + 2 + 2] cycloaddition of cyano-yne-allene scaffolds followed by a dehydrogenative process enabling the direct synthesis of unsaturated pyridine-containing compounds that can be conveniently converted to 2,6-naphthyridine derivatives is reported.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Alkadienes / chemistry*
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Alkynes / chemistry*
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Catalysis
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Cyclization
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Hydrogenation
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Molecular Structure
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Naphthyridines / chemical synthesis*
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Naphthyridines / chemistry*
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Organometallic Compounds / chemistry
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Rhodium / chemistry
Substances
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Alkadienes
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Alkynes
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Naphthyridines
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Organometallic Compounds
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propadiene
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Rhodium