The interactional behaviors and photo-physical properties of azo-salicylaldehyde ligands in solvents media

M S Zakerhamidi; K Nejati; S Alidousti; M Saati

doi:10.1016/j.saa.2015.06.015

The interactional behaviors and photo-physical properties of azo-salicylaldehyde ligands in solvents media

Spectrochim Acta A Mol Biomol Spectrosc. 2015 Nov 5:150:696-703. doi: 10.1016/j.saa.2015.06.015. Epub 2015 Jun 12.

Authors

M S Zakerhamidi¹, K Nejati², S Alidousti³, M Saati²

Affiliations

¹ Research Institute for Applied Physics and Astronomy, University of Tabriz, Tabriz, Iran. Electronic address: Zakerhamidi@tabrizu.ac.ir.
² Department of Chemistry, Payam Noor University, P.O. Box 19395-3697, Tehran, Islamic Republic of Iran.
³ Research Institute for Applied Physics and Astronomy, University of Tabriz, Tabriz, Iran.

PMID: 26093966
DOI: 10.1016/j.saa.2015.06.015

Abstract

A quantitative study of solvent effects on photo-physical properties of some azo-salicylaldehyde Schiff Bases ligands, with various substituent and alkyl group, was carried out, at room temperature. The solvatochromic behavior of these substances and their solvent-solute interactions, both specific and non-specific, was analyzed using linear solvation energy relationship concept, suggested by Kamlet-Taft. The ground and excited state dipole moments of these substances and their molecular resonance structures were also evaluated via solvatochromic shift method.

Keywords: Charge transfer; Dipole moment; Multi-parameter polarity scale; Salicylaldehyde azo Schiff Base.