Urinary concentrations of benzophenone-type ultraviolet light filters and semen quality

Fertil Steril. 2015 Oct;104(4):989-996. doi: 10.1016/j.fertnstert.2015.07.1129. Epub 2015 Aug 5.

Abstract

Objective: To assess benzophenone-type ultraviolet (UV) filter concentrations, chemicals used in sunscreen and personal care products, and semen endpoints.

Design: Cohort.

Setting: Not applicable.

Patient(s): A total of 413 men provided semen and urine samples, 2005-2009. Five UV filters were quantified (ng/mL) in urine using liquid chromatography-triple quadrupole mass spectrometry: BP-1 (2,4-dihydroxybenzophenone), BP-2 (2,2',4,4'-tetrahydroxybenzophenone), BP-3 (2-hydroxy-4-methoxybenzophenone), BP-8 (2,2'-dihydroxy-4-methoxybenzophenone), and 4-OH-BP (4-hydroxybenzophenone). Using linear regression, β-coefficients (β) and 95% confidence intervals (CIs) for each chemical dichotomized at the 75th percentile and Box-Cox transformed semen endpoint were estimated, after adjusting for age, body mass index, cotinine, season, and site.

Intervention(s): None.

Main outcome measure(s): Thirty-five semen endpoints.

Result(s): BP-2 was associated with diminished sperm concentration (β = -0.74; 95% CI -1.41, -0.08), straight (β = -4.57; 95% CI -8.95, -0.18) and linear movement (β = -3.15; 95% CI -6.01, -0.30), more immature sperm (β = 0.38; 95% CI 0.15, 0.62), and a decreased percentage of other tail abnormalities (β = -0.16; 95% CI -0.31, -0.01). BP-8 was associated with decreased hypo-osmotic swelling (β = -2.57; 95% CI -4.86, -0.29) and higher acrosome area (β = 1.14; 95% CI 0.01, 2.26). No associations were observed for BP-1, BP-3, or 4OH-BP.

Conclusion(s): The findings suggest that specific UV filters may be associated with some aspects of semen endpoints, but await future corroboration.

Keywords: Benzophenones; fecundity; semen; sperm; sunscreens.

Publication types

  • Research Support, N.I.H., Intramural

MeSH terms

  • Adult
  • Benzophenones / analysis
  • Benzophenones / classification
  • Benzophenones / urine*
  • DNA Fragmentation / drug effects
  • Humans
  • Longitudinal Studies
  • Male
  • Semen / drug effects
  • Semen / physiology
  • Semen Analysis*
  • Sunscreening Agents / analysis
  • Sunscreening Agents / metabolism*
  • Ultraviolet Rays
  • Urinalysis
  • Young Adult

Substances

  • Benzophenones
  • Sunscreening Agents
  • benzophenone