A new cassane diterpenoid from the seeds of Caesalpinia decapetala

J Asian Nat Prod Res. 2016;18(4):371-5. doi: 10.1080/10286020.2015.1055255. Epub 2015 Aug 13.

Abstract

Phytochemical investigation on the seeds of Caesalpinia decapetala led to the isolation of a new cassane diterpenoid with an unusual O bridge between C-19 and C-20, named phanginin Q (1), together with three known cassane diterpenoids, caesaljapin (2), caesaldekarin A (3), and caesaldekarin B (4). The structure of the new compound was elucidated by spectroscopic methods, including (1)H NMR, (13)C NMR, HSQC, (1)H - (1)H COSY, HMBC, NOESY, and HR-ESI-MS.

Keywords: Caesalpinia decapetala; Fabaceae; cassane diterpenoid; structure elucidation.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Caesalpinia / chemistry*
  • Diterpenes / chemistry
  • Diterpenes / isolation & purification*
  • Molecular Structure
  • Nuclear Magnetic Resonance, Biomolecular
  • Seeds / chemistry

Substances

  • Diterpenes
  • phanginin Q