Ferrier reaction in a deep eutectic solvent

Sunil M Rokade; Prakash M Bhate

doi:10.1016/j.carres.2015.07.015

Ferrier reaction in a deep eutectic solvent

Carbohydr Res. 2015 Oct 13:415:28-30. doi: 10.1016/j.carres.2015.07.015. Epub 2015 Jul 30.

Authors

Sunil M Rokade¹, Prakash M Bhate²

Affiliations

¹ Department of Dyestuff Technology, Institute of Chemical Technology (formerly UDCT), N. P. Marg, Matunga, Mumbai 400 019, Maharashtra, India.
² Department of Dyestuff Technology, Institute of Chemical Technology (formerly UDCT), N. P. Marg, Matunga, Mumbai 400 019, Maharashtra, India. Electronic address: pm.bhate@ictmumbai.edu.in.

PMID: 26279523
DOI: 10.1016/j.carres.2015.07.015

Abstract

A mild and efficient synthesis of 2,3-unsaturated sugar derivatives has been achieved by conducting the Ferrier reaction in a deep eutectic solvent (DES). A wide range of alcohols including primary, secondary, benzylic, and sugar-derived primary alcohols can be used. Advantages include good yields, shorter reaction times and recyclability of DES.

Keywords: 2,3-Unsaturated glycosides; Deep eutectic solvents; Ferrier reaction.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Alcohols / chemistry*
Glycosides / chemical synthesis*
Solvents / chemistry*

Substances

Alcohols
Glycosides
Solvents