1H, 15N and 13C resonance assignments of light organ-associated fatty acid-binding protein of Taiwanese fireflies

Biomol NMR Assign. 2016 Apr;10(1):71-4. doi: 10.1007/s12104-015-9640-0. Epub 2015 Sep 15.

Abstract

Fatty acid-binding proteins (FABPs) are a family of proteins that modulate the transfer of various fatty acids in the cytosol and constitute a significant portion in many energy-consuming cells. The ligand binding properties and specific functions of a particular type of FABP seem to be diverse and depend on the respective binding cavity as well as the cell type from which this protein is derived. Previously, a novel FABP (lcFABP; lc: Luciola cerata) was identified in the light organ of Taiwanese fireflies. The lcFABP was proved to possess fatty acids binding capabilities, especially for fatty acids of length C14-C18. However, the structural details are unknown, and the structure-function relationship has remained to be further investigated. In this study, we finished the (1)H, (15)N and (13)C chemical shift assignments of (15)N/(13)C-enriched lcFABP by solution NMR spectroscopy. In addition, the secondary structure distribution was revealed based on the backbone N, H, Cα, Hα, C and side chain Cβ assignments. These results can provide the basis for further structural exploration of lcFABP.

Keywords: Chemical shift assignments; Light organ; Luciola cerata; lcFABP.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Carbon Isotopes
  • Fatty Acid-Binding Proteins / chemistry*
  • Fireflies / metabolism*
  • Light*
  • Nitrogen Isotopes
  • Nuclear Magnetic Resonance, Biomolecular*
  • Protein Structure, Secondary
  • Tritium

Substances

  • Carbon Isotopes
  • Fatty Acid-Binding Proteins
  • Nitrogen Isotopes
  • Tritium