Fourier Deconvolution Methods for Resolution Enhancement in Continuous-Wave EPR Spectroscopy

Methods Enzymol. 2015:563:23-36. doi: 10.1016/bs.mie.2015.06.009. Epub 2015 Jul 2.

Abstract

An overview of resolution enhancement of conventional, field-swept, continuous-wave electron paramagnetic resonance spectra using Fourier transform-based deconvolution methods is presented. Basic steps that are involved in resolution enhancement of calculated spectra using an implementation based on complex discrete Fourier transform algorithms are illustrated. Advantages and limitations of the method are discussed. An application to an experimentally obtained spectrum is provided to illustrate the power of the method for resolving overlapped transitions.

Keywords: Apodization; Convolution; Deconvolution; Discrete Fourier transform; Electron paramagnetic resonance; Fourier filtering; Resolution enhancement; Window function.

MeSH terms

  • Algorithms
  • Electron Spin Resonance Spectroscopy / methods*
  • Fourier Analysis*