Ti2-Containing 18-Tungsto-2-Arsenate(III) Monolacunary Host and the Incorporation of a Phenylantimony(III) Guest

Kai-Yao Wang; Zhengguo Lin; Bassem S Bassil; Xiaolin Xing; Ali Haider; Bineta Keita; Guangjin Zhang; Cristian Silvestru; Ulrich Kortz

doi:10.1021/acs.inorgchem.5b01863

Ti2-Containing 18-Tungsto-2-Arsenate(III) Monolacunary Host and the Incorporation of a Phenylantimony(III) Guest

Inorg Chem. 2015 Nov 16;54(22):10530-2. doi: 10.1021/acs.inorgchem.5b01863. Epub 2015 Oct 22.

Authors

Kai-Yao Wang¹, Zhengguo Lin¹, Bassem S Bassil^{1

2}, Xiaolin Xing¹, Ali Haider¹, Bineta Keita³, Guangjin Zhang⁴, Cristian Silvestru⁵, Ulrich Kortz¹

Affiliations

¹ Department of Life Sciences and Chemistry, Jacobs University , P.O. Box 750561, 28725 Bremen, Germany.
² Department of Chemistry, Faculty of Sciences, University of Balamand , P.O. Box 100, Tripoli, Lebanon.
³ Laboratoire de Chimie-Physique, Université Paris-Sud, UMR 8000 CNRS , F-91405 Orsay, France.
⁴ Key Laboratory of Green Process and Engineering, Chinese Academy of Sciences , 100190 Beijing, China.
⁵ Department of Chemistry, Supramolecular Organic and Organometallic Chemistry Centre, Faculty of Chemistry and Chemical Engineering, Babes-Bolyai University , RO-400028 Cluj-Napoca, Romania.

PMID: 26492291
DOI: 10.1021/acs.inorgchem.5b01863

Abstract

The novel Ti2-containing, sandwich-type 18-tungsto-2-arsenate(III) [(Ti(IV)O)2(α-As(III)W9O33)2](14-) (1) was successfully synthesized by the reaction of [TiO](2+) species with [α-As(III)W9O33](9-). The monolacunary polyanion 1 is solution-stable, and a further reaction with 1 equiv of phenylantimony(III) dichloride resulted in [C6H5Sb(III)(Ti(IV)O)2(α-As(III)W9O33)2](12-) (2). Both polyanions 1 and 2 were structurally characterized in the solid state and solution. Electrochemical studies were also performed on both polyanions.

Publication types

Research Support, Non-U.S. Gov't