Enhancing distributive mixing of immiscible polyethylene/thermoplastic starch blend through zeolite ZSM-5 compounding sequence

Carbohydr Polym. 2016 Jan 20:136:812-9. doi: 10.1016/j.carbpol.2015.09.090. Epub 2015 Sep 30.

Abstract

The aim of this work was to explore the effect of zeolite ZSM-5 (ZSM5) incorporation sequence on the phase morphology, microstructure, and performance of polyethylene/thermoplastic starch (PE/TPS) films. Two processing sequences were used for preparing PE/TPS/ZSM5 composites at a weight ratio of PE to TPS of 70:30 and ZSM5 concentrations of 1-5 wt%: (i) melt compounding of PE with ZSM5 prior to melt blending with TPS (SI); and (ii) TPS was compounded with ZSM5 prior to blending with PE (SII). Distributive mixing and mechanical properties of PE/TPS blend were greatly enhanced when ZSM5 was incorporated via SII. These were caused by both the higher affinity between PE and ZSM5, compared to that of TPS and ZSM5, and the reduction of TPS viscosity after compounding with ZSM5, leading to migration of ZSM5 from TPS dispersed phase toward PE matrix and increase in breakup of TPS droplets during SII sequence.

Keywords: Blending sequence; Distributive mixing; Polyethylene; Thermoplastic starch; Viscosity; Zeolite.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Polyethylene / chemistry*
  • Starch / analogs & derivatives*
  • Starch / chemistry
  • Viscosity
  • Zeolites / chemistry*

Substances

  • ZSM-5 zeolite
  • Zeolites
  • Polyethylene
  • Starch