Photochromic Electret: A New Tool for Light Energy Harvesting

J Phys Chem Lett. 2012 Jan 5;3(1):51-7. doi: 10.1021/jz2014506. Epub 2011 Dec 13.

Abstract

In this paper, a photochromic electret for light energy harvesting is proposed and discussed. Such electret directly converts the photon energy into electric energy thanks to a polarization modulation caused by the photochromic reaction, which leads to a change in dipole moment. Theoretical concepts on which the photochromic electret is based are considered with an estimation of the effectiveness as a function of material properties. Finally, an electret based on a photochromic diarylethene is shown with the photoelectric characterization as a proof of concept device.

Keywords: capacitor; diarylethene; electret; energy harvesting; photochromism; polarization; poling.