Ultrathin metal nanowires have attracted wide attention becau se oftheir unique anisotropy and surface-to-volume effects. In this study, we use ultrathin Au nanowires as the templating core to epitaxially grow magnetic iron-cobalt (FeCo) shell through metal-redox with the control on their thickness and stoichiometry. Large surface-stress-induced phase transformation in Au nanowires triggers and stabilizes metastable tetragonal FeCo nanostructure to enhance its magnetic anisotropy and coercivity. Meanwhile, under illumination, plasmon-induced hotspot in ultrathin Au nanowires enables the light-control on magnetic characteristics of FeCo shell. This study demonstrates the feasibility of surface-stress-induced phase transformation to stabilize and control metastable nanostructures for enhanced magnetic anisotropy, which is one of the key properties of functional magnetic materials.
Keywords: FeCo; core/shell nanowires; magnetism; phase transformation.