Effect of resin and photoinitiator on color, translucency and color stability of conventional and low-shrinkage model composites

Dent Mater. 2016 Feb;32(2):183-91. doi: 10.1016/j.dental.2015.11.027. Epub 2015 Dec 29.

Abstract

Objective: To study the effect of a low-shrinkage methacrylate monomer and monoacylphosphine oxide photoinitiator on color, translucency, and color stability of model resin-based composites (RBCs).

Methods: Four micro-hybrid RBCs were prepared containing barium-glass fillers in bisphenol A-glycidyl-methacrylate (BisGMA) and triethyleneglycol-dimethacrylate (TEGDMA) or urethane-based low-shrinkage monomer FIT-852 (FIT; Esstech Inc.) and TEGDMA matrix. Camphorquinone (CQ)/amine or Lucirin TPO were used as photoinitiators. Commercial low-shrinkage RBCs (Charisma Diamond, Heraeus Kulzer and N'Durance, Septodont) and conventional RBCs (Tetric EvoCeram, Ivoclar Vivadent and Filtek Z250, 3M ESPE) were used as controls. Color and translucency were measured using Thermo Scientific Evolution (Thermo Fisher Scientific) and SpectroShade™ Micro (MHT Optic Research) spectrophotometers. Color stability was evaluated after immersion in black tea (pure, with milk or lemon) and distilled water. Data were analyzed using analyses of variance with Tukey's post-test (α=0.05).

Results: Photoinitiators had no significant effect on baseline color. Initially whiter FIT-based RBCs showed greater staining in all staining solutions than BisGMA-based RBCs. TPO-containing RBCs showed better color stability than CQ-containing RBCs irrespective of the base monomer. Tea and tea with lemon induced greatest color changes. Adding milk to tea significantly reduced material staining.

Significance: Urethane-based low-shrinkage monomer FIT and conventional BisGMA affected color, translucency and color stability of their respective RBCs. Despite being used in posterior teeth, low-shrinkage RBCs are expected to have favorable optical and esthetic properties. Manufacturers are urged to provide information on optical properties of monomers and monomer mixtures in their low-shrinkage RBCs to allow understanding of interaction with fillers and photoinitiators.

Keywords: BisGMA; Camphorquinone; Color; Composite; Low-shrinkage; Lucirin TPO; Photoinitiator; Resin; Staining; Translucency.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Camphor / analogs & derivatives
  • Camphor / chemistry
  • Citrus
  • Color*
  • Composite Resins / chemistry*
  • Materials Testing
  • Milk
  • Phase Transition
  • Phosphines / chemistry
  • Photoinitiators, Dental / chemistry*
  • Polyethylene Glycols / chemistry
  • Polymethacrylic Acids / chemistry
  • Surface Properties
  • Tea

Substances

  • Charisma composite resin
  • Composite Resins
  • Filtek Z250
  • N'Durance composite resin
  • Phosphines
  • Photoinitiators, Dental
  • Polymethacrylic Acids
  • Tea
  • Tetric EvoCeram
  • triethylene glycol dimethacrylate
  • Polyethylene Glycols
  • Camphor
  • camphorquinone