Cotton fabric with plasma pretreatment and ZnO/Carboxymethyl chitosan composite finishing for durable UV resistance and antibacterial property

Carbohydr Polym. 2016 Mar 15:138:106-13. doi: 10.1016/j.carbpol.2015.11.046. Epub 2015 Nov 19.

Abstract

ZnO/carboxymethyl chitosan (ZnO/CMCS) composite was prepared and confirmed by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), Ultraviolet-visible (UV-vis) spectroscopy, Scanning electron microscope (SEM), Transmission electron microscope (TEM). The combination of plasma pretreatment and ZnO/CMCS composite finishing was applied to provide durable UV resistance and antibacterial activity for cotton fabric. Cotton fabric was pretreated by cold oxygen plasma and the ZnO/CMCS composite finishing was carried out by pad-dry-cure. Cotton fabric was characterized by SEM, FTIR, UV resistance, antibacterial activity and Thermogravimetry (TG). SEM and FTIR analysis demonstrated the presence of ZnO/CMCS composite on cotton fabric and the increasing loading efficiency of ZnO/CMCS composite owing to plasma treatment. UV resistance and antibacterial activity of the finished cotton fabric were greatly improved, which increased with the increasing concentration of ZnO/CMCS composite. TG analysis indicated that the combined finishing of cotton fabric with plasma pretreatment and ZnO/CMCS composite could improve its thermal property. The finished cotton fabric exhibited an excellent laundering durability in UV resistance and antibacterial activity.

Keywords: Antibacterial activity; Cotton fabric; Durability; Plasma pretreatment; UV resistance; ZnO/Carboxymethyl chitosan composite.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Anti-Bacterial Agents / chemistry*
  • Anti-Bacterial Agents / pharmacology
  • Cellulose / chemistry*
  • Chitosan / analogs & derivatives*
  • Chitosan / chemistry
  • Klebsiella pneumoniae / drug effects
  • Microscopy, Electron, Scanning
  • Nanoparticles / chemistry
  • Spectroscopy, Fourier Transform Infrared
  • Staphylococcus aureus / drug effects
  • Thermogravimetry
  • Ultraviolet Rays*
  • X-Ray Diffraction
  • Zinc Oxide / chemistry*

Substances

  • Anti-Bacterial Agents
  • carboxymethyl-chitosan
  • Cellulose
  • Chitosan
  • Zinc Oxide