Phenol Dearomatization with Hypervalent Iodine Reagents

Stéphane Quideau; Laurent Pouységu; Philippe A Peixoto; Denis Deffieux

doi:10.1007/128_2015_665

Phenol Dearomatization with Hypervalent Iodine Reagents

Top Curr Chem. 2016:373:25-74. doi: 10.1007/128_2015_665.

Authors

Stéphane Quideau¹, Laurent Pouységu², Philippe A Peixoto², Denis Deffieux²

Affiliations

¹ Univ. Bordeaux, Institut des Sciences Moléculaires (CNRS-UMR 5255), 351 cours de la Libération, 33405, Talence Cedex, France. stephane.quideau@u-bordeaux.fr.
² Univ. Bordeaux, Institut des Sciences Moléculaires (CNRS-UMR 5255), 351 cours de la Libération, 33405, Talence Cedex, France.

PMID: 26809622
DOI: 10.1007/128_2015_665

Abstract

This chapter highlights recent developments in phenol dearomatization using organoiodane reagents and a selection of applications in natural product synthesis.

Keywords: Cyclohexadienones; Iodanes; Natural product synthesis; Phenol dearomatization; Quinones and quinols; Spirocyclizations.

MeSH terms

Alkaloids / chemical synthesis
Biological Products / chemical synthesis*
Cyclization
Indicators and Reagents*
Iodine Compounds / chemistry*
Phenol / chemistry*
Quinones / chemical synthesis

Substances

Alkaloids
Biological Products
Indicators and Reagents
Iodine Compounds
Quinones
Phenol