Characterization of organic matter in a sediment Core near the Mataripe refinery, Bahia-Brazil

Mar Pollut Bull. 2016 Apr 15;105(1):411-5. doi: 10.1016/j.marpolbul.2016.01.048. Epub 2016 Feb 23.

Abstract

A sediment core was taken from the Todos os Santos Bay, near the Mataripe Bahia-Brazil refinery. The results of dating, (210)Pb and (137)Cs methods, combined with organic indicators, Polycyclic aromatic hydrocarbons (PAHs), n-alkanes and total organic carbon (TOC), showed significant change with the start of production of the oil fields of Aratu, Itaparica and Dom João (1939-1947) and the construction of the Mataripe refinery (1949-1950). This event was marked by a series of significant changes, including an abrupt increase in TOC and the growth of PAH concentrations and the presence Unresolved/Resolved ratio (UR/R)>4 in n-alkanes fraction, which indicated that the contamination was of petrogenic origin. The δ(13)C of specific n-alkanes compounds showed gradual deplete with the depth.

Keywords: (210)Pb and (137)Cs geochronology; PAHs; Sediment core; δ(13)C of specific n-alkanes compounds.

MeSH terms

  • Alkanes / analysis
  • Brazil
  • Environmental Monitoring*
  • Geologic Sediments / chemistry*
  • Polycyclic Aromatic Hydrocarbons / analysis
  • Water Pollutants, Chemical / analysis*

Substances

  • Alkanes
  • Polycyclic Aromatic Hydrocarbons
  • Water Pollutants, Chemical