Resonant Carbon K-Edge Soft X-Ray Scattering from Lattice-Free Heliconical Molecular Ordering: Soft Dilative Elasticity of the Twist-Bend Liquid Crystal Phase

Phys Rev Lett. 2016 Apr 8;116(14):147803. doi: 10.1103/PhysRevLett.116.147803. Epub 2016 Apr 7.

Abstract

Resonant x-ray scattering shows that the bulk structure of the twist-bend liquid crystal phase, recently discovered in bent molecular dimers, has spatial periodicity without electron density modulation, indicating a lattice-free heliconical nematic precession of orientation that has helical glide symmetry. In situ study of the bulk helix texture of the dimer CB7CB shows an elastically confined temperature-dependent minimum helix pitch, but a remarkable elastic softness of pitch in response to dilative stresses. Scattering from the helix is not detectable in the higher temperature nematic phase.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.