Competitive inhibition of TRPV1-calmodulin interaction by vanilloids

FEBS Lett. 2016 Aug;590(16):2768-75. doi: 10.1002/1873-3468.12267. Epub 2016 Jul 12.

Abstract

There is enormous interest toward vanilloid agonists of the pain receptor TRPV1 in analgesic therapy, but the mechanisms of their sensory neuron-blocking effects at high or repeated doses are still a matter of debate. Our results have demonstrated that capsaicin and resiniferatoxin form nanomolar complexes with calmodulin, and competitively inhibit TRPV1-calmodulin interaction. These interactions involve the protein recognition interface of calmodulin, which is responsible for all of the cell-regulatory calmodulin-protein interactions. These results draw attention to a previously unknown vanilloid target, which may contribute to the explanation of the paradoxical pain-modulating behavior of these important pharmacons.

Keywords: TRPV1; calmodulin; capsaicin; resiniferatoxin; vanilloid.

Publication types

  • Letter
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Binding Sites
  • Calmodulin / chemistry
  • Calmodulin / genetics
  • Calmodulin / metabolism*
  • Capsaicin / metabolism
  • Capsaicin / pharmacology
  • Diterpenes / metabolism
  • Diterpenes / pharmacology
  • Humans
  • Pain / drug therapy
  • Pain / metabolism*
  • Protein Binding
  • Protein Conformation
  • Protein Interaction Maps / drug effects*
  • Protein Interaction Maps / genetics
  • Sensory Receptor Cells / drug effects
  • Sensory Receptor Cells / metabolism
  • TRPV Cation Channels / antagonists & inhibitors
  • TRPV Cation Channels / chemistry
  • TRPV Cation Channels / genetics
  • TRPV Cation Channels / metabolism*

Substances

  • Calmodulin
  • Diterpenes
  • TRPV Cation Channels
  • TRPV1 receptor
  • resiniferatoxin
  • Capsaicin