Precursor of α-Methylene-γ-butyrolactone Involved in the Insecticidal Activity of Thunberg Spiraea, Spiraea thunbergii

Biosci Biotechnol Biochem. 1999;63(1):152-4. doi: 10.1271/bbb.63.152.

Abstract

6-Tuliposide A {6-O-(4-hydroxy-α-methylenebutyryl)-D-glucopyranose} was isolated from thunberg spiraea (Spiraea thunbergii) leaves. Acid-hydrolysis of this compound generated tulipalin A (α-methylene-γ-butyrolactone). This compound is thus considered as a precursor of insecticidal tulipalin A.

Keywords: 6-tuliposide A {6-O-(4-hydroxy-α-methylenebutyryl)-D-glucopyranose}; insecticidal activity; thunberg spiraea (Spiraea thunbergii); α-methylene-γ-butyrolactone (tulipalin A).