Palladium-catalyzed Substitution Reaction of Allylic Derivatives with Tinacetylene

Biosci Biotechnol Biochem. 1999;63(1):238-42. doi: 10.1271/bbb.63.238.

Abstract

The substitution reaction of allylic derivatives (acetate, carbonate, and chloride) with tinacetylene proceeded in the presence of palladium as a catalyst to give a product having a 1-ene-4-yne system.

Keywords: allylic derivatives; allylic substitution; palladium catalyst; tinacetylene.