On the phosphorylase activity of GH3 enzymes: A β-N-acetylglucosaminidase from Herbaspirillum seropedicae SmR1 and a glucosidase from Saccharopolyspora erythraea

Carbohydr Res. 2016 Nov 29:435:106-112. doi: 10.1016/j.carres.2016.09.015. Epub 2016 Sep 23.

Abstract

A phosphorolytic activity has been reported for beta-N-acetylglucosaminidases from glycoside hydrolase family 3 (GH3) giving an interesting explanation for an unusual histidine as catalytic acid/base residue and suggesting that members from this family may be phosphorylases [J. Biol. Chem. 2015, 290, 4887]. Here, we describe the characterization of Hsero1941, a GH3 beta-N-acetylglucosaminidase from the endophytic nitrogen-fixing bacterium Herbaspirillum seropedicae SmR1. The enzyme has significantly higher activity against pNP-beta-D-GlcNAcp (Km = 0.24 mM, kcat = 1.2 s-1, kcat/Km = 5.0 mM-1s-1) than pNP-beta-D-Glcp (Km = 33 mM, kcat = 3.3 × 10-3 s-1, kcat/Km = 9 × 10-4 mM-1s-1). The presence of phosphate failed to significantly modify the kinetic parameters of the reaction. The enzyme showed a broad aglycone site specificity, being able to hydrolyze sugar phosphates beta-D-GlcNAc 1P and beta-D-Glc 1P, albeit at a fraction of the rate of hydrolysis of aryl glycosides. GH3 beta-glucosidase EryBI, that does not have a histidine as the general acid/base residue, also hydrolyzed beta-D-Glc 1P, at comparable rates to Hsero1941. These data indicate that Hsero1941 functions primarily as a hydrolase and that phosphorolytic activity is likely adventitious. The prevalence of histidine as a general acid/base residue is not predictive, nor correlative, with GH3 beta-N-acetylglucosaminidases having phosphorolytic activity.

Keywords: 2,4-Dinitrophenyl 2-fluoro-2-deoxy-beta-D-glucopyranoside (PubChem CID:445227); 2-acetamido-2-deoxy-α-D-glucopyranosyl fluoride (PubChem CID:53906163); 4-nitrophenyl 2-acetamido-2-deoxy-β-D-glucopyranoside (PubChem CID:102416); 4-nitrophenyl β-D-glucopyranoside (PubChem CID:92930); Chemical compounds; GH3 N-acetylglucosaminidases; Glycosidase; Glycoside hydrolase; Herbaspirillum seropedicae SmR1; Phospho-sugar; β-D-glucopyranosyl phosphate (PubChem CID:122250).

MeSH terms

  • Acetylglucosaminidase / chemistry
  • Acetylglucosaminidase / genetics
  • Acetylglucosaminidase / metabolism*
  • Bacterial Proteins / chemistry
  • Bacterial Proteins / genetics
  • Bacterial Proteins / metabolism
  • Catalytic Domain
  • Cloning, Molecular
  • Glucosidases / chemistry
  • Glucosidases / genetics
  • Glucosidases / metabolism*
  • Herbaspirillum / enzymology*
  • Herbaspirillum / genetics
  • Hydrolysis
  • Phosphorylation
  • Saccharopolyspora / enzymology*
  • Saccharopolyspora / genetics
  • Substrate Specificity

Substances

  • Bacterial Proteins
  • Glucosidases
  • Acetylglucosaminidase