New acetylenic acids and derivatives from the Basidiomycete Craterellus lutescens (Cantharellaceae)

Fitoterapia. 2016 Dec:115:177-181. doi: 10.1016/j.fitote.2016.10.006. Epub 2016 Oct 20.

Abstract

Five new acetylenic acid analogues, craterellynes A-E (1-5), together with three known compounds (6-8), were isolated from the fruiting bodies of Craterellus lutescens. Their structures were elucidated on the basis of spectroscopic and chemical means. The absolute configurations of 1-6 were determined by the modified Mosher method.

Keywords: Absolute configuration; Acetylenic acid; Craterellus lutescens.

MeSH terms

  • Agaricales / chemistry*
  • Alkynes / chemistry*
  • Alkynes / isolation & purification
  • Cell Line, Tumor
  • Fatty Acids, Unsaturated / chemistry*
  • Fatty Acids, Unsaturated / isolation & purification
  • Free Radical Scavengers
  • Fruiting Bodies, Fungal / chemistry
  • Humans
  • Molecular Structure

Substances

  • Alkynes
  • Fatty Acids, Unsaturated
  • Free Radical Scavengers
  • 2-hexadecynoic acid