Highly Efficient All-Inorganic Planar Heterojunction Perovskite Solar Cells Produced by Thermal Coevaporation of CsI and PbI2

J Phys Chem Lett. 2017 Jan 5;8(1):67-72. doi: 10.1021/acs.jpclett.6b02594. Epub 2016 Dec 12.

Abstract

We report here all inorganic CsPbI3 planar junction perovskite solar cells fabricated by thermal coevaporation of CsI and PbI2 precursors. The best devices delivered power conversion efficiency (PCE) of 9.3 to 10.5%, thus coming close to the reference MAPbI3-based devices (PCE ≈ 12%). These results emphasize that all inorganic lead halide perovskites can successfully compete in terms of photovoltaic performance with the most widely used hybrid materials such as MAPbI3.