Geochemical sources, forms and phases of soil contamination in an industrial city

Abstract

This study examines current soil contamination in an Australian industrial city, Newcastle. Public (roadside verges and parks) and private (homes) surface soils (n=170) contained metal(loid)s elevated above their respective Australian Health Investigation Levels (HIL). Lead (Pb), the most common contaminant in the city, exceeds the HIL for residential soils (HIL-A, 300mg/kg) in 88% of private soils (median: 1140mg/kg). In-vitro Pb bio-accessibility analysis of selected soils (n=11) using simulated gastric fluid showed a high affinity for Pb solubilisation (maximum Pb concentration: 5190mg/kg, equating to 45% Pb bio-accessibility). Highly soluble Pb-laden Fe- and Mn-oxides likely contribute to the bio-accessibility of the Pb. Public and private space surface soils contain substantially less radiogenic Pb (range: ²⁰⁸Pb/²⁰⁷Pb: 2.345-2.411, ²⁰⁶Pb/²⁰⁷Pb: 1.068-1.312) than local background soil (²⁰⁸Pb/²⁰⁷Pb: 2.489, ²⁰⁶Pb/²⁰⁷Pb: 1.198), indicating anthropogenic contamination from the less radiogenic Broken Hill type Pb ores (²⁰⁸Pb/²⁰⁷Pb: 2.319, ²⁰⁶Pb/²⁰⁷Pb: 1.044). Source apportionment using Pb isotopic ratio quantification and soil mineralogy indicate the city's historic copper and steel industries contributed the majority of the soil contaminants through atmospheric deposition and use of slag waste as fill material. High-temperature silicates and oxides combined with rounded particles in the soil are characteristic of smelter dust emissions. Additionally, a preliminary investigation of polycyclic aromatic hydrocarbons in soils, sometimes associated with ferrous metal smelting, coal processing or burning of fossil fuels, shows that these too pose a health exposure risk (calculated in comparison to benzo(a)pyrene: n=12, max: 13.5mg/kg, HIL: 3mg/kg).

Keywords: Bio-accessibility; Lead isotopes; Metal(loids); Mineralogy of metal-bearing particles; Newcastle; Soil.