Microwave-Initiated Facile Formation of Ni3Se4 Nanoassemblies for Enhanced and Stable Water Splitting in Neutral and Alkaline Media

Sengeni Anantharaj; Jeevarathinam Kennedy; Subrata Kundu

doi:10.1021/acsami.6b15980

Microwave-Initiated Facile Formation of Ni₃Se₄ Nanoassemblies for Enhanced and Stable Water Splitting in Neutral and Alkaline Media

ACS Appl Mater Interfaces. 2017 Mar 15;9(10):8714-8728. doi: 10.1021/acsami.6b15980. Epub 2017 Feb 28.

Authors

Sengeni Anantharaj¹, Jeevarathinam Kennedy, Subrata Kundu^{1

2}

Affiliations

¹ Academy of Scientific and Innovative Research (AcSIR), CSIR-Central Electrochemical Research Institute (CSIR-CECRI) Campus , New Delhi, India.
² Department of Materials Science and Mechanical Engineering, Texas A&M University , College Station, Texas 77843, United States.

PMID: 28215087
DOI: 10.1021/acsami.6b15980

Abstract

Molecular hydrogen (H₂) generation through water splitting with minimum energy loss has become practically possible due to the recent evolution of high-performance electrocatalysts. In this study, we fabricated, evaluated, and presented such a high-performance catalyst which is the Ni₃Se₄ nanoassemblies that can efficiently catalyze water splitting in neutral and alkaline media. A hierarchical nanoassembly of Ni₃Se₄ was fabricated by functionalizing the surface-cleaned Ni foam using NaHSe solution as the Se source with the assistance of microwave irradiation (300 W) for 3 min followed by 5 h of aging at room temperature (RT). The fabricated Ni₃Se₄ nanoassemblies were subjected to catalyze water electrolysis in neutral and alkaline media. For a defined current density of 50 mA cm^-2, the Ni₃Se₄ nanoassemblies required very low overpotentials for the oxygen evolution reaction (OER), viz., 232, 244, and 321 mV at pH 14.5, 14.0, and 13.0 respectively. The associated lower Tafel slope values (33, 30, and 40 mV dec^-1) indicate the faster OER kinetics on Ni₃Se₄ surfaces in alkaline media. Similarly, in the hydrogen evolution reaction (HER), for a defined current density of 50 mA cm^-2, the Ni₃Se₄ nanoassemblies required low overpotentials of 211, 206, and 220 mV at pH 14.5, 14.0, and 13.0 respectively. The Tafel slopes for HER at pH 14.5, 14.0, and 13.0 are 165, 156, and 128 mV dec^-1, respectively. A comparative study on both OER and HER was carried out with the state-of-the-art RuO₂ and Pt under identical experimental conditions, the results of which revealed that our Ni₃Se₄ is a far better high-performance catalyst for water splitting. Besides, the efficiency of Ni₃Se₄ nanoassemblies in catalyzing water splitting in neutral solution was carried out, and the results are better than many previous reports. With these amazing advantages in fabrication method and in catalyzing water splitting at various pH, the Ni₃Se₄ nanoassemblies can be an efficient, cheaper, nonprecious, and high-performance electrode for water electrolysis with low overpotentials.

Keywords: Ni3Se4 nanoassemblies; Tafel analysis; electrolysis; hydrogen evolution; overpotential; oxygen evolution; water splitting.