Composite System of Ag Nanoparticles and Metal-Organic Frameworks for the Capture and Conversion of Carbon Dioxide under Mild Conditions

Ning-Ning Zhu; Xiao-Huan Liu; Tao Li; Jian-Gong Ma; Peng Cheng; Guang-Ming Yang

doi:10.1021/acs.inorgchem.6b02855

Composite System of Ag Nanoparticles and Metal-Organic Frameworks for the Capture and Conversion of Carbon Dioxide under Mild Conditions

Inorg Chem. 2017 Mar 20;56(6):3414-3420. doi: 10.1021/acs.inorgchem.6b02855. Epub 2017 Mar 6.

Authors

Ning-Ning Zhu¹, Xiao-Huan Liu^{1

2}, Tao Li¹, Jian-Gong Ma¹, Peng Cheng^{1

3}, Guang-Ming Yang¹

Affiliations

¹ Department of Chemistry and Key Laboratory of Advanced Energy Material Chemistry, Nankai University , Tianjin 300071, China.
² College of Materials Science and Engineering, Hebei University of Engineering , Handan, Hebei 056038, China.
³ Collaborative Innovation Center of Chemical Science and Engineering (Tianjin) , Tianjin 300071, China.

PMID: 28263612
DOI: 10.1021/acs.inorgchem.6b02855

Abstract

The materials Ag@MIL-100(Fe) and Ag@UIO-66(Zr) are obtained for the capture and transformation of CO₂ into alkynyl carboxylic acids, which are environmental friendly, facile to synthesize, and exhibit excellent efficiency and reusability. The influence on the catalytic activity of such Ag@MOF systems by metal-organic frameworks' (MOFs) surface area, thermal, and chemical stability, especially the acid-base characteristics of the pores, are compared and discussed systematically.