New Chromophore Systems from Coumarin-Oxazol-5-one Combination

J Fluoresc. 2017 Jul;27(4):1413-1420. doi: 10.1007/s10895-017-2078-2. Epub 2017 Apr 22.

Abstract

Coumarin-oxazol-5-one (COX), 3a-d, were synthesized with 7-methoxy-2-oxo-2H-chromene-4-carbaldehyde and benzoylglycine derivatives. The characterizations of the COX derivatives by 1H NMR, FT-IR and elemental analysis were achieved. To obtain the photophysical data of the synthesized COX derivatives were used spectrophotometric and spectrofluorimetric methods. Evaluation of the absorption and emission properties of the structures was carried out in six different solvents. Maximum absorption and emission wavelengths (λ; nm), molar extinction coefficients (ε; cm-1 M-1), Stoke's shifts (ΔλST; nm) and quantum yields (ϕF), of the COX derivatives were declared.

Keywords: Chromophore; Coumarin; Oxazol-5-one.