A convenient and clean synthetic method for borasiloxanes by Pd-catalysed reaction of silanols with diborons

Aya Yoshimura; Michiyo Yoshinaga; Hiroshi Yamashita; Masayasu Igarashi; Shigeru Shimada; Kazuhiko Sato

doi:10.1039/c7cc02420g

A convenient and clean synthetic method for borasiloxanes by Pd-catalysed reaction of silanols with diborons

Chem Commun (Camb). 2017 May 30;53(43):5822-5825. doi: 10.1039/c7cc02420g.

Authors

Aya Yoshimura¹, Michiyo Yoshinaga, Hiroshi Yamashita, Masayasu Igarashi, Shigeru Shimada, Kazuhiko Sato

Affiliation

¹ National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1, Higashi, Tsukuba, Ibaraki 305-8565, Japan. hiro-yamashita@aist.go.jp.

PMID: 28497149
DOI: 10.1039/c7cc02420g

Abstract

Selective O-borylation of silanols with diborons took place in the presence of Pd catalysts to give the corresponding boryl silyl ethers in high yields.