Cancer Cell Discrimination Using Host-Guest "Doubled" Arrays

J Am Chem Soc. 2017 Jun 14;139(23):8008-8012. doi: 10.1021/jacs.7b03657. Epub 2017 Jun 1.

Abstract

We report a nanosensor that uses cell lysates to rapidly profile the tumorigenicity of cancer cells. This sensing platform uses host-guest interactions between cucurbit[7]uril and the cationic headgroup of a gold nanoparticle to non-covalently modify the binding of three fluorescent proteins of a multi-channel sensor in situ. This approach doubles the number of output channels to six, providing single-well identification of cell lysates with 100% accuracy. Significantly, this classification could be extended beyond the training set, determining the invasiveness of novel cell lines. The unique fingerprint of these cell lysates required minimal sample quantity (200 ng, ∼1000 cells), making the methodology compatible with microbiopsy technology.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Binding Sites
  • Biosensing Techniques*
  • Bridged-Ring Compounds / chemistry*
  • Cell Line, Tumor
  • Gold / chemistry
  • Humans
  • Imidazoles / chemistry*
  • Luminescent Proteins / chemistry*
  • Metal Nanoparticles / chemistry*
  • Molecular Structure
  • Nanotechnology*
  • Neoplasms / diagnostic imaging
  • Neoplasms / pathology*

Substances

  • Bridged-Ring Compounds
  • Imidazoles
  • Luminescent Proteins
  • cucurbit(7)uril
  • Gold