Abstract
A method for the allylic amidation of tautomerizable heterocycles was developed by a palladium catalyzed allylation reaction with 100% atom economy. A series of structurally diverse N-allylic substituted heterocycles can be synthesized in good yields with high chemo-, regio-, and stereoselectivities under mild conditions.
MeSH terms
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Alkynes / chemistry*
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Allyl Compounds / chemical synthesis*
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Allyl Compounds / chemistry
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Amides / chemical synthesis*
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Amides / chemistry
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Catalysis
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Heterocyclic Compounds / chemistry*
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Molecular Structure
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Organometallic Compounds / chemistry*
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Palladium / chemistry*
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Stereoisomerism
Substances
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Alkynes
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Allyl Compounds
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Amides
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Heterocyclic Compounds
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Organometallic Compounds
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Palladium