Channel interference in multiphoton absorption

J Chem Phys. 2017 Jun 28;146(24):244116. doi: 10.1063/1.4990438.

Abstract

We extend the theory of channel interference to higher-order multiphoton absorption processes. We derive an explicit expression for channel interference in a three-photon absorption process and propose a general scheme for deriving such expressions for multiphoton absorption processes of any order. Based on this general scheme, we derive and analyze the simplest few-state models for multiphoton absorption in centrosymmetric molecules and discuss the criteria for maximizing the corresponding multiphoton absorption strengths.