Abstract
Oxidative [1,2]-Brook rearrangements via hypervalent silicon intermediates induced by photoredox-catalyzed single-electron transfer have been achieved, permitting the formation of reactive radical species that can engage in alkylations and arylations.
Publication types
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Research Support, N.I.H., Extramural
MeSH terms
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Alkylation
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Catalysis
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Electron Transport
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Hydrocarbons, Aromatic / chemical synthesis*
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Hydrocarbons, Aromatic / chemistry
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Molecular Structure
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Organosilicon Compounds / chemistry*
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Oxidation-Reduction
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Photochemical Processes
Substances
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Hydrocarbons, Aromatic
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Organosilicon Compounds