Some observations on the greenhouse effect at the Earth's surface

Spectrochim Acta A Mol Biomol Spectrosc. 2018 Jan 5:188:127-134. doi: 10.1016/j.saa.2017.06.051. Epub 2017 Jul 5.

Abstract

It is shown that the greenhouse gases carbon dioxide and water vapour reflect back to the surface, all IR radiation originating at the surface within their respective spectral bands. This reflection occurs in a very thin layer at the surface, not much over 12cm in thickness. Heat is lost from the surface by heat exchange with the atmosphere and by loss of radiation. About 52% of radiation leaves the surface in two principal window regions but this is not enough to account for the earth's equilibrium temperature. This window radiation seems to disappear quite quickly and is replaced by black body radiation. It is this which eventually contributes to the earth's radiation balance, and has to originate approximately between 40 and 50km altitude where the temperature is about correct, near 255K. Doubling the CO2 concentration increases the surface temperature by about 0.9°C and this need not have any influence higher up in the atmosphere. The surface temperature seems indeed to have no direct influence on the earth's external radiation balance.

Keywords: Earth's surface; Greenhouse effect; Radiation balance.