Ligand- and Solvent-Controlled Regio- and Chemodivergent Carbonylative Reactions

Jin-Bao Peng; Xiao-Feng Wu

doi:10.1002/anie.201709807

Ligand- and Solvent-Controlled Regio- and Chemodivergent Carbonylative Reactions

Angew Chem Int Ed Engl. 2018 Jan 26;57(5):1152-1160. doi: 10.1002/anie.201709807. Epub 2018 Jan 5.

Authors

Jin-Bao Peng¹, Xiao-Feng Wu^{1

2}

Affiliations

¹ Department of Chemistry, Zhejiang Sci-Tech University, Xiasha Campus, Hangzhou, 310018, P. R. China.
² Leibniz-Institut für Katalyse e.V. an der, Universität Rostock, Albert-Einstein-Straße 29a, 18059, Rostock, Germany.

PMID: 29024272
DOI: 10.1002/anie.201709807

Abstract

The development of highly selective procedures is one of the core goals in organic chemistry. Among the known organic transformations, carbonylation reactions present an ideal choice for the preparation of carbonyl-containing compounds. In this review, the recent achievements on the control of the selectivity for carbonylation reactions have been summarized. The effects of ligands, solvents, and bases on the selectivity are been discussed.

Keywords: carbon monoxide; carbonylation; selectivity; synthetic methods; transition metals.

Publication types

Review
Research Support, Non-U.S. Gov't