A novel 2-D Mn selenidostannate(iv) incorporating high-nuclear Mn clusters with spin canting behavior

Jian Zhou; Hong Xiao; Hua-Hong Zou; Xing Liu

doi:10.1039/c7dt03331a

A novel 2-D Mn selenidostannate(iv) incorporating high-nuclear Mn clusters with spin canting behavior

Dalton Trans. 2017 Nov 28;46(46):16009-16013. doi: 10.1039/c7dt03331a.

Authors

Jian Zhou¹, Hong Xiao, Hua-Hong Zou, Xing Liu

Affiliation

¹ Chongqing Key Laboratory of Inorganic Functional Materials, College of Chemistry, Chongqing Normal University, Chongqing, 401331, P.R. China. Jianzhou888888@163.com.

PMID: 29120468
DOI: 10.1039/c7dt03331a

Abstract

A solvothermal reaction of SnCl₄·5H₂O, Mn and Se in ethanolamine (Hea) yielded a novel 2-D Mn selenidostannate(iv) [Mn₇(ea)₆(SnSe₄)₂]_n (1), which not only provides the first example of the incorporation of a hepta-nuclear Mn cluster [Mn₇(ea)₆]⁸⁺ into a selenidostannate(iv) framework, but also shows unusual spin canting behavior.