Mirror materials (perfect specular surfaces such as polished metal) and glass materials (transparent and refraction media) are quite commonly encountered in everyday life. The human visual system can discriminate these complex distorted images formed by reflection or transmission of the surrounding environment even though they do not intrinsically possess surface colour. In this study, we determined the cues that aid mirror and glass discrimination. From video analysis, we found that glass objects have more opposite motion components relative to the direction of object rotation. Then, we hypothesised a model developed using motion transparency because motion information is not only present on the front side, but also on the rear side of the object surface in the glass material object. In materials judging experiments, we found that human performance with rotating video stimuli is higher than that with static stimuli (simple images). Subsequently, we compared the developed model derived from motion coherency to human rating performance for transparency and specular reflection. The model sufficiently identified the different materials using dynamic information. These results suggest that the visual system relies on dynamic cues that indicate the difference between mirror and glass.