Microwave-assisted sintering synthesis of greenish-yellow emitting Sr2 SiO4 :Eu2+ phosphors

Luminescence. 2018 Sep;33(6):1081-1086. doi: 10.1002/bio.3511. Epub 2018 Jun 21.

Abstract

Europium ion (Eu2+ ) doped Sr2 SiO4 phosphors with greenish-yellow emission were synthesized using microwave-assisted sintering. The phase structure and photoluminescence (PL) properties of the obtained phosphor samples were investigated. The PL excitation spectra of the Sr2 SiO4 :Eu2+ phosphors exhibited a broad band in the range of 260 nm to 485 nm with a maximum at 361 nm attributed to the 5f-4d allowed transition of the Eu2+ ions. Under an excitation at 361 nm, the Sr2 SiO4 :Eu2+ phosphor exhibited a greenish-yellow emission peak at 541 nm with an International-Commission-on-Illumination (CIE) chromaticity of (0.3064, 0.4772). The results suggest that the microwave-assisted sintering method is promising for the synthesis of phosphors owing to the decreased sintering time without the use of additional reductive agents.

Keywords: Sr2SiO4:Eu2+; microwave-assisted sintering; phosphor.

MeSH terms

  • Europium / chemistry*
  • Luminescence*
  • Luminescent Agents / chemistry*
  • Microwaves*
  • Particle Size
  • Photochemical Processes
  • Silicates / chemistry*
  • Strontium / chemistry*
  • Surface Properties

Substances

  • Luminescent Agents
  • Silicates
  • Europium
  • Strontium