Crystal structure and Hirshfeld surface analysis of N-[(2-hy-droxy-naphthalen-1-yl)(3-methyl-phen-yl)meth-yl]acetamide

Acta Crystallogr E Crystallogr Commun. 2018 Jun 21;74(Pt 7):1002-1005. doi: 10.1107/S2056989018008423. eCollection 2018 Jul 1.

Abstract

The title compound, C20H19NO2, is of inter-est as a precursor to biologically active substituted quinolines and related compounds. This compound crystallizes with two independent mol-ecules (A and B) in the asymmetric unit. The dihedral angles between mean planes of the methyl-phenyl ring and the naphthalene ring system are 78.32 (6) and 84.70 (6)° in mol-ecules A and B, respectively. In the crystal, the anti-ferroelectric packing of mol-ecules A and B is of an ABBAABB type along the b-axis direction. The crystal structure features N-H⋯O, O-H⋯O and weak C-H⋯O hydrogen bonds, which link the mol-ecules into infinite chains propagating along the b-axis direction.

Keywords: 1-amino­alkyl-2-naphthols; Hirshfeld surface; crystal structure; hydrogen bonding.

Grants and funding

This work was funded by Université Constantine 1, Algeria grant .