Monitoring Ultraviolet Radiation Dosage Based on a Luminescent Lanthanide Metal-Organic Framework

Xiaoyan Li; Yaxing Wang; Jian Xie; Xuemiao Yin; Mark A Silver; Yawen Cai; Hailong Zhang; Lanhua Chen; Guoqing Bian; Juan Diwu; Zhifang Chai; Shuao Wang

doi:10.1021/acs.inorgchem.8b01193

Monitoring Ultraviolet Radiation Dosage Based on a Luminescent Lanthanide Metal-Organic Framework

Inorg Chem. 2018 Aug 6;57(15):8714-8717. doi: 10.1021/acs.inorgchem.8b01193. Epub 2018 Jul 25.

Authors

Xiaoyan Li¹, Yaxing Wang¹, Jian Xie¹, Xuemiao Yin¹, Mark A Silver¹, Yawen Cai¹, Hailong Zhang¹, Lanhua Chen¹, Guoqing Bian², Juan Diwu¹, Zhifang Chai^{1

3}, Shuao Wang¹

Affiliations

¹ State Key Laboratory of Radiation Medicine and Protection, School for Radiological and interdisciplinary Sciences (RAD-X) and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions , Soochow University , Suzhou 215123 , China.
² College of Chemistry, Chemical Engineering and Materials Science , Soochow University , Suzhou 215123 , China.
³ Laboratory of Nuclear Energy Chemistry and Key Laboratory for Biomedical Effects of Nanomaterials and Nanosafety, Institute of High Energy Physics , Chinese Academy of Sciences , Beijing 100049 , China.

PMID: 30043611
DOI: 10.1021/acs.inorgchem.8b01193

Abstract

A luminescent lanthanide metal-organic framework [Tb₇(OH)₈(H₂O)₆(IDA)₃(COO)₃]·4Cl·2H₂O (Tb-IDA, IDA = iminodiacetic acid) was hydrothermally synthesized and structurally characterized. Monitoring ultraviolet radiation was achieved by correlating the dosage with the luminescence color change in doped Gd₉₉Tb_0.1Eu_0.9-IDA compound. A linear relationship is developed across a broad range from blue to yellow within a CIE chromaticity diagram.