During the last few years, a great amount of oxygen-vacant materials have been synthetized and applied as electrodes for electrochemical storage. The presence of oxygen vacancies leads to an increase in the conductivity and the diffusion coefficient; consequently, the controllable synthesis of oxygen vacancy plays an important role in improving the electrochemical performance, including achieving high specific capacitance, high power density, high energy density, and good cycling stability of the electrode materials for batteries. This review mainly focuses on research progress in the preparation of oxygen-vacant nanostructures and the application of materials with oxygen vacancies in various batteries (such as lithium-ion, lithium-oxygen, and sodium-ion batteries). Challenges related to and opportunities for oxygen-vacant materials are also provided.
Keywords: batteries; oxygen defects; vacancy.
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