Optical design of spectrally selective interlayers for perovskite/silicon heterojunction tandem solar cells

Opt Express. 2018 Sep 3;26(18):A750-A760. doi: 10.1364/OE.26.00A750.

Abstract

Monolithic perovskite/c-Si tandem solar cells have the potential to exceed the Shockley-Queisser limit for single junction solar cells. However, reflection losses at internal interfaces play a crucial role for the overall efficiency of the tandem devices. Significant reflection losses are caused by the charge selective contacts which have a significantly lower refractive index compared to the absorber materials. Here, we present an approach to overcome a significant part of these reflection losses by introducing a multilayer stack between the top and bottom cell which shows spectrally selective transmission/reflection behavior. The layer stack is designed and optimized by optical simulations using transfer matrix method and a genetic algorithm. The incident sun light is split into a direct part and an isotropic diffuse part. The tandem solar cell with interlayer shows an absolute improvement of short-circuit current density of 0.82 mA/cm2.