Olefin Bifunctionalization: A Visible-light Photoredox-catalyzed Aryl Alkoxylation of Olefins

Chem Asian J. 2019 Jan 4;14(1):121-124. doi: 10.1002/asia.201801211. Epub 2018 Dec 6.

Abstract

Olefin bifunctionalization is a facile route to obtain complex molecules from abundant and commercially available olefin feedstocks. Visible light together with a catalytic amount of tris(bipyridine)ruthenium salt catalyzes the aryl alkoxylation of styrenes with aryl diazonium salts in alcohol solvents via a photoredox process. The scope of this proposed reaction with respect to various aryl diazonium salts and styrenes has been investigated.

Keywords: alkoxylation; bifunctionalization; olefins; photoredox catalyst; visible light.

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