Abstract
Marine natural products and biologically active compounds often contain cyclic ether units. Thus, regio- and stereoselective construction of these structures has long been a topic of interest in organic synthesis. This review summarizes new synthetic approaches to polycyclic ether natural products utilizing the features of chemical elements.
Keywords:
1,3-transposition; gold catalysis; maitotoxin; polyether; rhenium catalysis.
MeSH terms
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Animals
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Biological Products / chemical synthesis*
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Biological Products / chemistry
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Catalysis
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Chemistry, Organic / methods
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Elements*
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Ethers, Cyclic / chemical synthesis*
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Ethers, Cyclic / chemistry
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Gold
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Hydrophobic and Hydrophilic Interactions
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Marine Biology*
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Marine Toxins / chemical synthesis*
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Marine Toxins / chemistry
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Mice
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Molecular Conformation
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Organic Chemistry Phenomena
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Oxocins / chemical synthesis*
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Oxocins / chemistry
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Rhenium / chemistry
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Stereoisomerism
Substances
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Biological Products
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Elements
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Ethers, Cyclic
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Marine Toxins
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Oxocins
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Rhenium
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Gold
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maitotoxin