Crystal structure of (E)-2,6-dimeth-oxy-4-{[(4-meth-oxy-phen-yl)imino]-meth-yl}phenol

Md Serajul Haque Faizi; Mohamad Nadeem Lone; Necmi Dege; Sergey Malinkin; Tatiana Yu Sliva

doi:10.1107/S2056989018013713

Crystal structure of (E)-2,6-dimeth-oxy-4-{[(4-meth-oxy-phen-yl)imino]-meth-yl}phenol

Acta Crystallogr E Crystallogr Commun. 2018 Oct 5;74(Pt 11):1540-1542. doi: 10.1107/S2056989018013713. eCollection 2018 Nov 1.

Authors

Md Serajul Haque Faizi¹, Mohamad Nadeem Lone², Necmi Dege³, Sergey Malinkin⁴, Tatiana Yu Sliva⁴

Affiliations

¹ Department of Chemistry, Langat Singh College, Babasaheb Bhimrao Ambedkar Bihar University, Muzaffarpur, Bihar, India.
² Department of Chemistry, Govt. College For Women, Udhampur, Jammu and Kashmir 182 101, India.
³ Ondokuz Mayıs University, Arts and Sciences Faculty, Department of Physics, Atakum 55139 Samsun, Turkey.
⁴ Department of Chemistry, National Taras Shevchenko University of Kiev, 64/13, Volodymyrska Street, City of Kyiv, 01601, Ukraine.

Abstract

In the title compound, C₁₆H₁₇NO₄, the dihedral angle between benzene rings is 72.7 (2)°. The meth-oxy groups are rotated by 2.4 (2) and -4.9 (2) (benzil-idene moiety) and by 5.6 (3)° (aniline moiety) relative to the adjacent benzene ring. In the crystal, the mol-ecules are linked into chains along [101] through C-H⋯O and O-H⋯N hydrogen bonds.

Keywords: 4-hydroxy-3,5-dimethoxybenzaldehyde; 4-methoxyaniline; crystal structure; syringaldehyde.