Microporous polymer membranes have been widely studied because of their excellent separation performance. Among them, polymers of intrinsic micro-porosity (PIMs) have been regarded as a potential next-generation membrane material for their ultra-permeable characteristics and their solution-processing ability. Therefore, many reviews have been reported on gas separation and monomers for the preparation of PIMs. This review aims to provide an overview of the structure-solubility property. Different structures such as non-network and network macromolecular structure made of different monomers have been reviewed. Then their solubility with different structures and different separation applications such as nanofiltration, pervaporation, and gas/vapor separation are summarized. Lastly, we also provide our perspectives on the challenges and future directions of the microporous polymer membrane for the structure-property relationship, anti-physical aging, and more.
Keywords: microporous polymer membrane; separation performance; solubility; structure.