Adsorption of micropollutants present in surface waters onto polymeric resins: Impact of resin type and water matrix on performance

Abstract

The occurrence of micropollutants in water resources is raising substantial concerns, worldwide. These pollutants may have adverse impacts on the aquatic ecosystem and human health. Even though activated carbon is commonly used as an adsorbent to remove micropollutants from water, its low removal of hydrophilic components, energy-intensive regeneration procedure and slow adsorption can impair its applicability. Polymeric resins have been suggested as an effective alternative adsorbent due to their high porosity and accessible adsorption sites, significant adsorption concentration and stable chemical properties. In this work, we evaluated the performance of five commercially available polymeric resins (including two ion exchange resins) for the removal of nine selected micropollutants in water. More specifically, we investigated the effect of polymeric resin type and concentration, contact time and water matrix on the removal efficiency of five pharmaceuticals, two pesticides and two endocrine disruptors of high current concern (diclofenac, sulfamethoxazole, fluoxetine, caffeine, carbamazepine, 17-β estradiol, norethindrone, atrazine and desesthylatrazine). Results presented herein indicated that two hydrophobic polymeric resins can effectively adsorb over 80% of the targeted micropollutants within 30 min when the resin concentration was higher than 2.5 mL L^-1. The adsorption data were well described with the Freundlich isotherm and the pseudo-second order kinetic model very well described the kinetic process of the selected micropollutants onto the polymeric resins. Moreover, we observed that increasing the synthetic water temperature from 4 to 22 °C led to a marginally higher micropollutant uptake and the presence of natural organic matter had no noted impact on the efficiency of the resins in removing the tested micropollutants when the resin dosage was 5.4 mL L^-1. On the basis of these promising results, we conclude that polymeric resins are a promising alternative to activated carbon for micropollutants sorption in drinking water treatment.

Keywords: Adsorption; Hormones; Micropollutants in water resources; Pesticides; Pharmaceuticals; Polymeric resins.