Rapid Growth of TiO₂ Nanoflowers via Low-Temperature Solution Process: Photovoltaic and Sensing Applications

Materials (Basel). 2019 Feb 14;12(4):566. doi: 10.3390/ma12040566.

Abstract

This paper reports the rapid synthesis, characterization, and photovoltaic and sensing applications of TiO₂ nanoflowers prepared by a facile low-temperature solution process. The morphological characterizations clearly reveal the high-density growth of a three-dimensional flower-shaped structure composed of small petal-like rods. The detailed properties confirmed that the synthesized nanoflowers exhibited high crystallinity with anatase phase and possessed an energy bandgap of 3.2 eV. The synthesized TiO₂ nanoflowers were utilized as photo-anode and electron-mediating materials to fabricate dye-sensitized solar cell (DSSC) and liquid nitroaniline sensor applications. The fabricated DSSC demonstrated a moderate conversion efficiency of ~3.64% with a maximum incident photon to current efficiency (IPCE) of ~41% at 540 nm. The fabricated liquid nitroaniline sensor demonstrated a good sensitivity of ~268.9 μA mM-1 cm-2 with a low detection limit of 1.05 mM in a short response time of 10 s.

Keywords: TiO2 nanoflowers; chemical sensor; nitroaniline; photovoltaic device; sensitivity.