Surfactant-Thermal Synthesis of Amino Acid-Templated Zinc Phosphates with 3-Connected Nets Related to Zeolite ABW

Lijuan Huang; Jing Li; Hongmei Zeng; Guohong Zou; Yan Zhao; Ling Huang; Jian Bi; Daojiang Gao; Zhien Lin

doi:10.1021/acs.inorgchem.9b00391

Surfactant-Thermal Synthesis of Amino Acid-Templated Zinc Phosphates with 3-Connected Nets Related to Zeolite ABW

Inorg Chem. 2019 Apr 1;58(7):4089-4092. doi: 10.1021/acs.inorgchem.9b00391. Epub 2019 Mar 12.

Authors

Lijuan Huang^{1

2}, Jing Li¹, Hongmei Zeng¹, Guohong Zou¹, Yan Zhao², Ling Huang², Jian Bi², Daojiang Gao², Zhien Lin¹

Affiliations

¹ College of Chemistry , Sichuan University , Chengdu 610064 , China.
² College of Chemistry and Materials Science , Sichuan Normal University , Chengdu 610068 , China.

PMID: 30859821
DOI: 10.1021/acs.inorgchem.9b00391

Abstract

Two crystalline zinc phosphates, formulated as Zn(HPO₄)(dl-C₅H₉NO₂) (SCU-3) and Zn(HPO₄)(C₂H₅NO₂) (SCU-10), were prepared under surfactant-thermal conditions using amino acids as structure-directing agents. Different from traditional zeolites with 4-connected nets, the two compounds have different 3-connected nets related to zeolite ABW. Powder second-harmonic-generation (SHG) measurement shows that SCU-10 is a nonlinear optically active solid with an SHG efficiency about 1.4 times that of KH₂PO₄.