Polyvinyl formal (PVF) was first synthesized via the reaction of poly(vinyl alcohol) (PVA) and formaldehyde. The synthesized PVF exhibits a high decomposition temperature, glass transition temperature, and low melting point compared to pristine PVA. The synthesized PVF can be melt processed at temperatures much lower than PVA. Poly(propylene carbonate) (PPC) and the as-made PVF were melt blended in a Haake mixer. The mechanical properties, thermal behaviors, and morphologies of PPC/PVF blends were investigated. Compared to the pure PPC, PPC/PVF blends show higher tensile strength and Vicat softening temperature. Thermogravimetric (TGA) result reveals that the thermal stabilities of PPC/PVF blends decreased with the increase of the content of PVF. Scanning electron microscopy (SEM) observation indicates that the interfacial compatibility of the PVF and PPC matrix is better than that of the PVA and PPC matrix. The PPC/PVF blends show much better comprehensive properties compared to pure commercial PPC, which provides a practical way to extend the application of PPC copolymer.
Keywords: blends; poly(propylene carbonate); poly(vinyl alcohol); poly(vinyl formal).