Foam as a self-assembling amorphous photonic band gap material

Proc Natl Acad Sci U S A. 2019 May 7;116(19):9202-9207. doi: 10.1073/pnas.1820526116. Epub 2019 Apr 24.

Abstract

We show that slightly polydisperse disordered 2D foams can be used as a self-assembled template for isotropic photonic band gap (PBG) materials for transverse electric (TE) polarization. Calculations based on in-house experimental and simulated foam structures demonstrate that, at sufficient refractive index contrast, a dry foam organization with threefold nodes and long slender Plateau borders is especially advantageous to open a large PBG. A transition from dry to wet foam structure rapidly closes the PBG mainly by formation of bigger fourfold nodes, filling the PBG with defect modes. By tuning the foam area fraction, we find an optimal quantity of dielectric material, which maximizes the PBG in experimental systems. The obtained results have a potential to be extended to 3D foams to produce a next generation of self-assembled disordered PBG materials, enabling fabrication of cheap and scalable photonic devices.

Keywords: disordered photonic materials; hyperuniformity; metamaterials; photonic band gap; self-assembly.